|
|
geranyl_diphosphate <=> myrcene + diphosphate
|
4.2.3.15
myrcene synthase
4.2.3.20
(R)-limonene synthase
|
–
–
|
MK
|
|
BRENDA:
BR22830
KEGG:
R02009
MetaCyc:
RXN-5110
|
|
|
|
geranyl_diphosphate <=> (-)-limonene + diphosphate
|
4.2.3.101
7-epi-sesquithujene synthase
4.2.3.102
sesquithujene synthase
4.2.3.118
2-methylisoborneol synthase
4.2.3.16
(4S)-limonene synthase
|
–
–
–
–
|
MK
|
|
BRENDA:
BR22831;
BS398891
KEGG:
R02013
MetaCyc:
4.2.3.16-RXN
|
|
|
|
geranyl_diphosphate <=> (+)-bornyl-diphosphate
|
5.5.1.8
(+)-bornyl diphosphate synthase
|
–
|
BMK
|
|
BRENDA:
BR266
KEGG:
R02007
MetaCyc:
GERANYL-DIPHOSPHATE-CYCLASE-RXN
|
|
|
|
geranyl_diphosphate + 4-hydroxybenzoate <=> 3-geranyl-4-hydroxybenzoate + diphosphate
|
2.5.1.39
4-hydroxybenzoate polyprenyltransferase
2.5.1.93
4-hydroxybenzoate geranyltransferase
|
–
–
|
MK
|
|
BRENDA:
BR47433
KEGG:
R05000;
R09040
MetaCyc:
RXN-8920
|
|
|
|
geranyl_diphosphate + isopentenyl_diphosphate <=> (2E,6E)-farnesyl_diphosphate + diphosphate
|
2.5.1.1
dimethylallyltranstransferase
2.5.1.10
(2E,6E)-farnesyl diphosphate synthase
2.5.1.29
geranylgeranyl diphosphate synthase
|
–
–
–
|
BMK
|
|
BRENDA:
BR47562
KEGG:
R02003
MetaCyc:
FPPSYN-RXN
SABIO-RK:
2041
|
|
|
|
dimethylallyl_diphosphate + isopentenyl_diphosphate <=> geranyl_diphosphate + diphosphate
|
2.5.1.1
dimethylallyltranstransferase
2.5.1.10
(2E,6E)-farnesyl diphosphate synthase
2.5.1.29
geranylgeranyl diphosphate synthase
2.5.1.67
chrysanthemyl diphosphate synthase
2.5.1.69
lavandulyl diphosphate synthase
|
–
–
–
–
–
|
BMK
|
|
BRENDA:
BR47563
KEGG:
R01658
MetaCyc:
GPPSYN-RXN
SABIO-RK:
1793
|
|
|
|
geranyl_diphosphate <=> (+)-limonene + diphosphate
|
4.2.3.20
(R)-limonene synthase
|
–
|
MK
|
|
BRENDA:
BR47586
KEGG:
R06120
MetaCyc:
4.2.3.20-RXN
|
|
|
|
geranyl_diphosphate + H2O <=> (-)-endo-fenchol + diphosphate
|
4.2.3.10
(-)-endo-fenchol synthase
|
–
|
MK
|
|
BRENDA:
BR48348;
BS430215
KEGG:
R02004
MetaCyc:
4.2.3.10-RXN
|
|
|
|
geranyl_diphosphate + H2O <=> Sabinene_hydrate + diphosphate
|
4.2.3.11
sabinene-hydrate synthase
|
–
|
K
|
|
BRENDA:
BR48349
KEGG:
R02006
MetaCyc:
4.2.3.11-RXN
|
|
|
|
geranyl_diphosphate + H2O <=> (3S)-linalool + diphosphate
|
4.2.3.25
S-linalool synthase
4.2.3.48
(3S,6E)-nerolidol synthase
|
–
–
|
MK
|
|
BRENDA:
BR48697
KEGG:
R07631
MetaCyc:
4.2.3.25-RXN
SABIO-RK:
14621
|
|
|
|
geranyl_diphosphate + H2O <=> (3R)-linalool + diphosphate
|
4.2.3.25
S-linalool synthase
4.2.3.26
R-linalool synthase
|
–
–
|
MK
|
|
BRENDA:
BR48698;
BS398886
KEGG:
R07632
MetaCyc:
4.2.3.26-RXN
|
|
|
|
geranyl_diphosphate + isopentenyl_diphosphate <=> diphosphate + (2Z,6E)-farnesyl_diphosphate
|
2.5.1.68
(2Z,6E)-farnesyl diphosphate synthase
|
–
|
MK
|
|
BRENDA:
BR48805
KEGG:
R08528
MetaCyc:
2.5.1.68-RXN
|
|
|
|
geranyl_diphosphate + isopentenyl_diphosphate <=> nonaprenyl_diphosphate + diphosphate
|
2.5.1.84
all-trans-nonaprenyl diphosphate synthase [geranyl-diphosphate specific]
|
–
|
BMK
|
|
BRENDA:
BR49314
KEGG:
R09250
MetaCyc:
TRANS-OCTAPRENYLTRANSTRANSFERASE-RXN
|
|
|
|
geranyl_diphosphate <=> beta-phellandrene + diphosphate
|
4.2.3.52
(4S)-beta-phellandrene synthase (geranyl-diphosphate-cyclizing)
|
–
|
M
|
|
BRENDA:
BR49346
MetaCyc:
RXN-5143
|
|
|
|
S-adenosyl-L-methionine + geranyl_diphosphate <=> S-adenosyl-L-homocysteine + (E)-2-methylgeranyl_diphosphate + H+
|
2.1.1.255
geranyl diphosphate 2-C-methyltransferase
|
–
|
M
|
|
BRENDA:
BR49888
KEGG:
R09940
MetaCyc:
RXN-12975
SABIO-RK:
14860
|
|
|
|
geranyl_diphosphate <=> (E)-beta-ocimene + diphosphate
|
4.2.3.106
(E)-beta-ocimene synthase
|
–
|
M
|
|
BRENDA:
BR49951
KEGG:
R09962
MetaCyc:
RXN-5109
|
|
|
|
geranyl_diphosphate <=> (+)-car-3-ene + diphosphate
|
4.2.3
4.2.3.107
(+)-car-3-ene synthase
|
–
–
|
MK
|
|
BRENDA:
BR49952
KEGG:
R08395;
R09963
MetaCyc:
RXN-8565;
RXN-8575
SABIO-RK:
14099
|
|
|
|
geranyl_diphosphate <=> terpinolene + diphosphate
|
4.2.3.113
terpinolene synthase
|
–
|
M
|
|
BRENDA:
BR49953
KEGG:
R02010
MetaCyc:
RXN-5108
|
|
|
|
geranyl_diphosphate + H2O <=> geraniol + diphosphate
|
3.1.7.11
geranyl diphosphate diphosphatase
3.1.7.3
monoterpenyl-diphosphatase
4.2.3.104
alpha-humulene synthase
|
–
–
–
|
BMK
|
|
BRENDA:
BR50059
KEGG:
R08396
MetaCyc:
RXN-17103;
RXN-8618
SABIO-RK:
12967
|
|
|
|
geranyl_diphosphate <=> tricyclene + diphosphate
|
4.2.3.105
tricyclene synthase
|
–
|
M
|
|
BRENDA:
BR50068
KEGG:
R09961
MetaCyc:
RXN-5121
|
|
|
|
geranyl_diphosphate + H2O <=> 1,8-cineole + diphosphate
|
4.2.3.108
1,8-cineole synthase
|
–
|
M
|
|
BRENDA:
BR50071
KEGG:
R09964
MetaCyc:
RXN-12980
SABIO-RK:
13134
|
|
|
|
geranyl_diphosphate <=> (-)-sabinene + diphosphate
|
4.2.3
4.2.3.109
(-)-sabinene synthase
|
–
–
|
M
|
|
BRENDA:
BR50072
KEGG:
R09965
MetaCyc:
RXN-12981;
RXN-5103
|
|
|
|
geranyl_diphosphate <=> (+)-sabinene + diphosphate
|
4.2.3.110
(+)-sabinene synthase
|
–
|
|
|
BRENDA:
BR50073
KEGG:
R09966
MetaCyc:
RXN-12982
SABIO-RK:
14100
|
|
|
|
geranyl_diphosphate + H2O <=> (-)-alpha-terpineol + diphosphate
|
4.2.3.108
1,8-cineole synthase
4.2.3.111
(-)-alpha-terpineol synthase
4.2.3.112
(+)-alpha-terpineol synthase
|
–
–
–
|
K
|
|
BRENDA:
BR50074;
BS444324
KEGG:
R06421
MetaCyc:
RXN-5101
|
|
|
|
geranyl_diphosphate + H2O <=> (+)-alpha-terpineol + diphosphate
|
4.2.3.112
(+)-alpha-terpineol synthase
|
–
|
|
|
BRENDA:
BR50075
KEGG:
R09968
MetaCyc:
RXN-12983
|
|
|
|
geranyl_diphosphate <=> gamma-terpinene + diphosphate
|
4.2.3.114
gamma-terpinene synthase
|
–
|
|
|
BRENDA:
BR50077
KEGG:
R09969
MetaCyc:
RXN-8547
|
|
|
|
geranyl_diphosphate <=> alpha-terpinene + diphosphate
|
4.2.3.115
alpha-terpinene synthase
|
–
|
|
|
BRENDA:
BR50078
KEGG:
R09970
MetaCyc:
RXN-8546
|
|
|
|
geranyl_diphosphate <=> (+)-camphene + diphosphate
|
4.2.3.116
(+)-camphene synthase
4.2.3.20
(R)-limonene synthase
|
–
–
|
MK
|
|
BRENDA:
BR50079
KEGG:
R09971
MetaCyc:
RXN-8576
|
|
|
|
geranyl_diphosphate <=> (-)-camphene + diphosphate
|
4.2.3
4.2.3.116
(+)-camphene synthase
4.2.3.117
(-)-camphene synthase
|
–
–
–
|
MK
|
|
BRENDA:
BR50080
KEGG:
R02011;
R09972
MetaCyc:
RXN-5142
|
|
|
|
geranyl_diphosphate <=> (-)-alpha-pinene + diphosphate
|
4.2.3.119
(-)-alpha-pinene synthase
4.2.3.121
(+)-alpha-pinene synthase
|
–
–
|
MK
|
|
BRENDA:
BR50082
KEGG:
R05765
MetaCyc:
RXN-5106
|
|
|
|
geranyl_diphosphate <=> (-)-beta-pinene + diphosphate
|
4.2.3.120
(-)-beta-pinene synthase
4.2.3.122
(+)-beta-pinene synthase
|
–
–
|
MK
|
|
BRENDA:
BR50083
KEGG:
R05766
MetaCyc:
RXN-5107
|
|
|
|
geranyl_diphosphate <=> (+)-alpha-pinene + diphosphate
|
4.2.3.121
(+)-alpha-pinene synthase
4.2.3.20
(R)-limonene synthase
|
–
–
|
|
|
BRENDA:
BR50084
KEGG:
R09974
MetaCyc:
RXN-8563
|
|
|
|
geranyl_diphosphate <=> (+)-beta-pinene + diphosphate
|
4.2.3.122
(+)-beta-pinene synthase
|
–
|
|
|
BRENDA:
BR50085
KEGG:
R09975
MetaCyc:
RXN-8564
|
|
|
|
geranyl_diphosphate + 2,4-dihydroxy-6-pentylbenzoate <=> cannabigerolate + diphosphate
|
2.5.1.102
geranyl-pyrophosphate---olivetolic acid geranyltransferase
|
–
|
MK
|
|
BRENDA:
BR50302
KEGG:
R10176
MetaCyc:
RXN-7853
|
|
|
|
geranyl_diphosphate <=> (-)-bornyl_diphosphate
|
5.5.1.22
(-)-bornyl diphosphate synthase
5.5.1.8
(+)-bornyl diphosphate synthase
|
–
–
|
BM
|
|
BRENDA:
BR50817
KEGG:
R10509
MetaCyc:
RXN-13002
|
|
|
|
geranyl_diphosphate + 2-O-methyl-3-methylflaviolin <=> diphosphate + 6-(3,7-dimethylocta-1,6-dien-3-yl)-5,7-dihydroxy-2-methoxy-3-methylnaphthalene-1,4-dione
|
2.5.1.124
6-linalyl-2-O,3-dimethylflaviolin synthase
|
–
|
|
|
BRENDA:
BR50881
KEGG:
R11086
MetaCyc:
RXN-15422
|
|
|
|
geranyl_diphosphate + 2-O-methyl-3-methylflaviolin <=> diphosphate + 7-[[(2E)-3,7-dimethylocta-2,6-dien-1-yl]oxy]-5-hydroxy-2-methoxy-3-methylnaphthalene-1,4-dione
|
2.5.1.125
7-geranyloxy-5-hydroxy-2-methoxy-3-methylnaphthalene-1,4-dione synthase
|
–
|
|
|
BRENDA:
BR50882
KEGG:
R11087
MetaCyc:
RXN-15425
|
|
|
|
geranyl_diphosphate + flaviolin + H+ <=> 3-linalylflaviolin + diphosphate
|
2.5.1.123
flaviolin linalyltransferase
2.5.1.125
7-geranyloxy-5-hydroxy-2-methoxy-3-methylnaphthalene-1,4-dione synthase
|
–
–
|
|
|
BRENDA:
BR51045;
BS426430
KEGG:
R10969
MetaCyc:
RXN-15421
|
|
|
|
geranyl_diphosphate + H2O <=> geranyl_phosphate + phosphate + H+
|
3.6.1.68
geranyl diphosphate phosphohydrolase
|
–
|
MK
|
|
BRENDA:
BR51531
KEGG:
R11551
MetaCyc:
RXN-17104
|
|
|
|
geranyl_diphosphate + umbelliferone <=> diphosphate + 8-geranylumbelliferone
|
2.5.1.138
coumarin 8-geranyltransferase
|
–
|
|
|
BRENDA:
BR51971
KEGG:
R11602
MetaCyc:
RXN-18495
|
|
|
|
geranyl_diphosphate + esculetin <=> diphosphate + 8-geranylesculetin
|
2.5.1.138
coumarin 8-geranyltransferase
|
–
|
|
|
BRENDA:
BR51972
KEGG:
R11603
MetaCyc:
RXN-18496
|
|
|
|
geranyl_diphosphate <=> (1R,4S,5R)-4-methyl-1-propan-2-ylbicyclo[3.1.0]hex-2-ene + diphosphate
|
4.2.3.177
beta-thujene synthase
|
–
|
|
|
BRENDA:
BR52203
KEGG:
R11842
MetaCyc:
RXN-18863
|
|
|
|
3-[(Z)-2-isocyanoethenyl]-1H-indole + geranyl_diphosphate <=> 3-geranyl-3-[(Z)-2-isocyanoethenyl]-1H-indole + diphosphate
|
2.5.1.146
3-geranyl-3-[(Z)-2-isocyanoethenyl]indole synthase
|
–
|
M
|
|
BRENDA:
BR52418
KEGG:
R12089
MetaCyc:
RXN-19272
|
|
|
|
geranyl_diphosphate <=> (Z)-beta-ocimene + diphosphate
|
4.2.3
4.2.3.B69
|
–
–
|
M
|
|
BRENDA:
BR52642
MetaCyc:
RXN-5123
|
|
|
|
Selenophosphate + 5-methylaminomethyl-2-thiouridine34_in_tRNA + geranyl_diphosphate + H2O <=> 5-methylaminomethyl-2-selenouridine34_in_tRNA + (2E)-3,7-dimethylocta-2,6-diene-1-thiol + diphosphate + phosphate
|
2.9.1.3
tRNA 2-selenouridine synthase
|
–
|
|
|
BRENDA:
BR53030
MetaCyc:
RXN0-2281
|
|
|
|
geranyl_diphosphate + 5-methylaminomethyl-2-thiouridine34_in_tRNA <=> 5-methylaminomethyl-2-(S-geranyl)thiouridine34_in_tRNA + diphosphate
|
2.9.1.3
tRNA 2-selenouridine synthase
|
–
|
M
|
|
BRENDA:
BR53031
MetaCyc:
RXN-20755
|
|
|
|
geranyl_diphosphate + 1,4-dihydroxy-2-naphthoate <=> a_demethylmenaquinol + diphosphate + CO2
|
2.5.1.74
1,4-dihydroxy-2-naphthoate polyprenyltransferase
|
–
|
BK
|
|
BRENDA:
BR49120
KEGG:
R10757
|
|
|
|
geranyl_diphosphate + 2 isopentenyl_diphosphate <=> geranylgeranyl_diphosphate + 2 diphosphate
|
2.5.1.29
geranylgeranyl diphosphate synthase
|
–
|
|
|
BRENDA:
BS355477
SABIO-RK:
13678
|
|
|
|
geranyl_diphosphate <=> nerol
|
not assigned
|
–
|
|
|
KEGG:
R08393
|
|
|
|
geranyl_diphosphate <=> neral
|
not assigned
|
–
|
K
|
|
KEGG:
R08394
|
|
|
|
geranyl_diphosphate <=> citronellol
|
not assigned
|
–
|
K
|
|
KEGG:
R08397
|
|
|
|
geranyl_diphosphate <=> citral
|
not assigned
|
–
|
K
|
|
KEGG:
R08398
|
|
|
|
geranyl_diphosphate <=> (R)-citronellal
|
not assigned
|
–
|
K
|
|
KEGG:
R08399
|
|
|
|
Selenophosphoric_acid + geranyl_diphosphate + tRNA_containing_5-methylaminomethyl-2-thiouridylate + H2O <=> 5-methylaminomethyl-2-selenouridine34_in_tRNA + (2E)-3,7-dimethylocta-2,6-diene-1-thiol + diphosphate + phosphate
|
2.9.1.3
tRNA 2-selenouridine synthase
|
–
|
|
|
KEGG:
R12580
|
|
|
|
geranyl_diphosphate + tRNA_containing_5-methylaminomethyl-2-thiouridylate <=> 5-methylaminomethyl-2-(S-geranyl)thiouridine34_in_tRNA + diphosphate
|
2.9.1.3
tRNA 2-selenouridine synthase
|
–
|
|
|
KEGG:
R12581
|
|
|
|
deoxyhumulone + geranyl_diphosphate + dimethylallyl_diphosphate + H+ <=> adhyperforin + diphosphate
|
not assigned
|
–
|
M
|
|
MetaCyc:
RXN-13549
|
|
|
|
5-hydroxyanthrotainin + geranyl_diphosphate <=> previridicatumtoxin + diphosphate
|
2.5.1
|
–
|
M
|
|
MetaCyc:
RXN-16582
|
|
|
|
(-)-indolactam_V + geranyl_diphosphate <=> lyngbyatoxin_A + diphosphate
|
2.5.1
|
–
|
M
|
|
MetaCyc:
RXN-17002
|
|
|
|
Selenophosphate + 5-carboxymethylaminomethyl-2-thiouridine34_in_tRNA + geranyl_diphosphate + H2O <=> 5-carboxymethylaminomethyl-2-selenouridine34_in_tRNA + (2E)-3,7-dimethylocta-2,6-diene-1-thiol + diphosphate + phosphate
|
2.9.1.3
tRNA 2-selenouridine synthase
|
–
|
|
|
MetaCyc:
RXN-20762
|
|
|
|
geranyl_diphosphate + L-glutamate <=> N-geranyl-L-glutamate + diphosphate
|
2.5.1
|
–
|
M
|
|
MetaCyc:
RXN-20869
|
|
|
|
geranyl_diphosphate <=> (+)-alpha-thujene + diphosphate
|
4.2.3
|
–
|
|
|
MetaCyc:
RXN-5105
|
|
|
|
geranyl_diphosphate <=> (+)-2-carene + diphosphate
|
4.2.3
|
–
|
|
|
MetaCyc:
RXN-5122
|
|
|
|
geranyl_diphosphate <=> (+)-2-carene + diphosphate
|
4.2.3
|
–
|
|
|
MetaCyc:
RXN-8577
|
|
|
|
deoxycohumulone + dimethylallyl_diphosphate + geranyl_diphosphate + H+ <=> hyperforin + diphosphate
|
not assigned
|
–
|
M
|
|
MetaCyc:
RXN-9135
|
|
|
|
geranyl_diphosphate + 3 isopentenyl_diphosphate <=> (2E,6E,10E,14E)-geranylfarnesyl_diphosphate + 3 diphosphate
|
2.5.1.81
geranylfarnesyl diphosphate synthase
|
–
|
|
|
BRENDA:
BS409482
|
|
|
|
geranyl_diphosphate + 9 isopentenyl_diphosphate <=> 9 diphosphate + monotrans,nonacis-undecaprenyl_diphosphate
|
2.5.1.B35
|
–
|
|
|
BRENDA:
BS428635
|
|
|
|
geranyl_diphosphate + n isopentenyl_diphosphate <=> n diphosphate + di-trans,poly-cis-polyprenyl_diphosphate
|
2.5.1.87
ditrans,polycis-polyprenyl diphosphate synthase [(2E,6E)-farnesyl diphosphate specific]
|
–
|
|
|
BRENDA:
BS407225
|
|
|
|
isopentenyl_diphosphate + geranyl_diphosphate <=> undecaprenyl_diphosphate + decaprenyl_diphosphate + diphosphate
|
2.5.1.31
ditrans,polycis-undecaprenyl-diphosphate synthase [(2E,6E)-farnesyl-diphosphate specific]
|
–
|
|
|
BRENDA:
BS354390
|
|
|
|
geranyl_diphosphate + isopentenyl_diphosphate <=> diphosphate + decaprenyl_diphosphate + nonaprenyl_diphosphate + octaprenyl_diphosphate
|
2.5.1.86
trans,polycis-decaprenyl diphosphate synthase
|
–
|
|
|
BRENDA:
BS409489
|
|
|
|
geranyl_diphosphate + 4 isopentenyl_diphosphate <=> 4 diphosphate + all-trans-hexaprenyl_diphosphate
|
2.5.1.30
heptaprenyl diphosphate synthase
2.5.1.82
hexaprenyl diphosphate synthase [geranylgeranyl-diphosphate specific]
2.5.1.83
hexaprenyl diphosphate synthase [(2E,6E)-farnesyl-diphosphate specific]
|
–
–
–
|
|
|
BRENDA:
BS409483
|
|
|
|
geranyl_diphosphate + n isopentenyl_diphosphate <=> n diphosphate + trans,poly-cis-polyprenyl_diphosphate
|
2.5.1.88
trans,polycis-polyprenyl diphosphate synthase [(2Z,6E)-farnesyl diphosphate specific]
|
–
|
|
|
BRENDA:
BS409490
|
|
|
|
geranyl_diphosphate + 8 isopentenyl_diphosphate <=> 8 diphosphate + decaprenyl_diphosphate
|
2.5.1.91
all-trans-decaprenyl-diphosphate synthase
|
–
|
|
|
BRENDA:
BS409485
|
|
|
|
dimethylallyl_diphosphate + isopentenyl_diphosphate <=> geranyl_diphosphate + (2E,6E)-farnesyl_diphosphate + geranylgeranyl_diphosphate + diphosphate
|
2.5.1.29
geranylgeranyl diphosphate synthase
|
–
|
|
|
BRENDA:
BS397056
|
|
|
|
dimethylallyl_diphosphate + isopentenyl_diphosphate <=> (2E,6E)-farnesyl_diphosphate + geranyl_diphosphate + diphosphate
|
2.5.1.1
dimethylallyltranstransferase
2.5.1.10
(2E,6E)-farnesyl diphosphate synthase
|
–
–
|
|
|
BRENDA:
BS409312
|
|
|
|
geranyl_diphosphate + dimethylallyl_diphosphate <=> diphosphate + geranylgeranyl_diphosphate
|
2.5.1.29
geranylgeranyl diphosphate synthase
|
–
|
|
|
BRENDA:
BS423585
|
|
|
|
dimethylallyl_diphosphate + geranyl_diphosphate <=> diphosphate + (2E,6E)-farnesyl_diphosphate
|
2.5.1.10
(2E,6E)-farnesyl diphosphate synthase
|
–
|
|
|
BRENDA:
BS421953
|
|
|
|
geranyl_diphosphate + but-3-enyl_diphosphate <=> diphosphate + 3-desmethyl_farnesyl_diphosphate
|
2.5.1.29
geranylgeranyl diphosphate synthase
|
–
|
|
|
BRENDA:
BS437570
|
|
|
|
geranyl_diphosphate + (3S)-3-(1H-indol-3-ylmethyl)-3,4-dihydro-1H-1,4-benzodiazepine-2,5-dione <=> (3S)-3-([6-[(2Z)-2-ethylidene-6-methylhept-5-en-1-yl]-1H-indol-3-yl]methyl)-3,4-dihydro-1H-1,4-benzodiazepine-2,5-dione + (3S)-3-([7-[(2Z)-7-methylocta-2,6-dien-1-yl]-1H-indol-3-yl]methyl)-3,4-dihydro-1H-1,4-benzodiazepine-2,5-dione + diphosphate
|
2.5.1.1
dimethylallyltranstransferase
|
–
|
|
|
BRENDA:
BS437564
|
|
|
|
geranyl_diphosphate + (3S,6R)-3-(4-hydroxybenzyl)-6-(1H-indol-3-ylmethyl)piperazine-2,5-dione <=> (3R,6S)-3-([6-[(2Z)-3,7-dimethylocta-2,6-dien-1-yl]-1H-indol-3-yl]methyl)-6-[(4-hydroxyphenyl)methyl]piperazine-2,5-dione + (3R,6S)-3-([7-[(2Z)-3,7-dimethylocta-2,6-dien-1-yl]-1H-indol-3-yl]methyl)-6-[(4-hydroxyphenyl)methyl]piperazine-2,5-dione + diphosphate
|
2.5.1.1
dimethylallyltranstransferase
|
–
|
|
|
BRENDA:
BS437565
|
|
|
|
geranyl_diphosphate + cyclo-(L-Trp-L-Tyr) <=> (3R,6R)-3-([6-[(2Z)-3,7-dimethylocta-2,6-dien-1-yl]-1H-indol-3-yl]methyl)-6-[(4-hydroxyphenyl)methyl]piperazine-2,5-dione + (3S,6S)-3-([7-[(2Z)-3,7-dimethylocta-2,6-dien-1-yl]-1H-indol-3-yl]methyl)-6-[(4-hydroxyphenyl)methyl]piperazine-2,5-dione + diphosphate
|
2.5.1.1
dimethylallyltranstransferase
|
–
|
|
|
BRENDA:
BS437568
|
|
|
|
geranyl_diphosphate + (R)-benzodiazepinedione <=> (3R)-3-([6-[(2Z)-2-ethylidene-6-methylhept-5-en-1-yl]-1H-indol-3-yl]methyl)-3,4-dihydro-1H-1,4-benzodiazepine-2,5-dione + diphosphate
|
2.5.1.1
dimethylallyltranstransferase
|
–
|
|
|
BRENDA:
BS437569
|
|
|
|
geranyl_diphosphate + homogentisate <=> diphosphate + (3-geranyl-2,5-dihydroxyphenyl)acetate
|
2.5.1.117
homogentisate solanesyltransferase
|
–
|
|
|
BRENDA:
BS428636
|
|
|
|
3-[(E)-2-isocyanoethenyl]-1H-indole + geranyl_diphosphate <=> 2-[(2E)-3,7-dimethylocta-2,6-dien-1-yl]-3-[(Z)-2-isocyanoethenyl]-1H-indole + 3-[(2E)-3,7-dimethylocta-2,6-dien-1-yl]-3-[(Z)-2-isocyanoethenyl]-3H-indole
|
2.5.1.146
3-geranyl-3-[(Z)-2-isocyanoethenyl]indole synthase
|
–
|
|
|
BRENDA:
BS444168
|
|
|
|
geranyl_diphosphate + 3-propylbut-3-enyl_diphosphate <=> diphosphate + 3-propylfarnesyl_diphosphate
|
2.5.1.29
geranylgeranyl diphosphate synthase
|
–
|
|
|
BRENDA:
BS437572
|
|
|
|
geranyl_diphosphate + cyclo-L-Trp-L-Leu <=> (3S,6S)-3-([6-[(2E)-3,7-dimethylocta-2,6-dien-1-yl]-1H-indol-3-yl]methyl)-6-(2-methylpropyl)piperazine-2,5-dione + (3S,6S)-3-([7-[(2E)-3,7-dimethylocta-2,6-dien-1-yl]-1H-indol-3-yl]methyl)-6-(2-methylpropyl)piperazine-2,5-dione + diphosphate
|
2.5.1.1
dimethylallyltranstransferase
|
–
|
|
|
BRENDA:
BS437567
|
|
|
|
geranyl_diphosphate + cyclo-L-tryptophan-L-tryptophan <=> (3S,6S)-3-([6-[(2E)-3,7-dimethylocta-2,6-dien-1-yl]-1H-indol-3-yl]methyl)-6-[(1H-indol-3-yl)methyl]piperazine-2,5-dione + (3S,6S)-3-([7-[(2Z)-3,7-dimethylocta-2,6-dien-1-yl]-1H-indol-3-yl]methyl)-6-[(1H-indol-3-yl)methyl]piperazine-2,5-dione + diphosphate
|
2.5.1.1
dimethylallyltranstransferase
|
–
|
|
|
BRENDA:
BS437566
|
|
|
|
geranyl_diphosphate + flaviolin <=> diphosphate + 3-[(2E)-3,7-dimethylocta-2,6-dien-1-yl]-2,5,7-trihydroxynaphthalene-1,4-dione
|
2.5.1.124
6-linalyl-2-O,3-dimethylflaviolin synthase
2.5.1.125
7-geranyloxy-5-hydroxy-2-methoxy-3-methylnaphthalene-1,4-dione synthase
|
–
–
|
|
|
BRENDA:
BS426429
|
|
|
|
geranyl_diphosphate + flaviolin <=> diphosphate + 2-[(2E)-3,7-dimethylocta-2,6-dien-1-yl]-3,6,7-trihydroxynaphthalene-1,4-dione
|
2.5.1.124
6-linalyl-2-O,3-dimethylflaviolin synthase
|
–
|
|
|
BRENDA:
BS426432
|
|
|
|
geranyl_diphosphate + 4-hydroxybenzoate <=> 4-[[(2E)-3,7-dimethylocta-2,6-dien-1-yl]oxy]benzoic_acid
|
2.5.1.123
flaviolin linalyltransferase
|
–
|
|
|
BRENDA:
BS430210
|
|
|
|
geranyl_diphosphate + phloroisovalerophenone <=> diphosphate + 3-methyl-1-[2,4,6-trihydroxy-3-geranylphenyl]propan-1-one
|
2.5.1.136
2-acylphloroglucinol 4-prenyltransferase
|
–
|
|
|
BRENDA:
BS439558
|
|
|
|
geranyl_diphosphate + 2-cyclohexenylethyl_diphosphate <=> (S)-geranylcyclohexylideneethyl_diphosphate + diphosphate
|
2.5.1.1
dimethylallyltranstransferase
2.5.1.10
(2E,6E)-farnesyl diphosphate synthase
|
–
–
|
|
|
BRENDA:
BS409481
|
|
|
|
geranyl_diphosphate + 1,3-dihydroxynaphthalene <=> desulforedoxin + pyruvoyl_cofactor
|
2.5.1.123
flaviolin linalyltransferase
|
–
|
|
|
BRENDA:
BS430209
|
|
|
|
geranyl_diphosphate + 2-O-methyl-3-methylflaviolin <=> diphosphate + 7-[[(2E)-3,7-dimethylocta-2,6-dien-1-yl]oxy]-5-hydroxy-2-methoxy-3-methylnaphthalene-1,4-dione + 6-prenyl-2-methoxy-3-methylflaviolin
|
2.5.1.124
6-linalyl-2-O,3-dimethylflaviolin synthase
|
–
|
|
|
BRENDA:
BS424811
|
|
|
|
geranyl_diphosphate + 3-Ethylbut-3-enyl_diphosphate <=> diphosphate + 3-ethylfarnesyl_diphosphate
|
2.5.1.29
geranylgeranyl diphosphate synthase
|
–
|
|
|
BRENDA:
BS437571
|
|
|
|
geranyl_diphosphate + dansyl-GCVLS <=> dansyl-G-(S-geranyl)CVLS + diphosphate
|
2.5.1.58
protein farnesyltransferase
|
–
|
|
|
BRENDA:
BS409486
|
|
|
|
geranyl_diphosphate + H2O <=> geraniol + phosphate
|
3.1.3.76
lipid-phosphate phosphatase
|
–
|
|
|
BRENDA:
BS379792
|
|
|
|
geranyl_diphosphate + H2O <=> (Z)-2,3-dihydro-3-(1H-imidazol-1-yl)-2-(1-butyl)-4H-1-benzopyran-4-one_oxime + diphosphate
|
4.2.3.11
sabinene-hydrate synthase
|
–
|
|
|
BRENDA:
BS430211
|
|
|
|
geranyl_diphosphate + H2O <=> (Z)-trans-2,3-dihydro-3-(1H-imidazol-1-yl)-2-(1-pentyl)-4H-1-benzopyran-4-one_oxime + diphosphate
|
4.2.3.11
sabinene-hydrate synthase
|
–
|
|
|
BRENDA:
BS430212
|
|
|
|
geranyl_diphosphate + H2O <=> (E)-sabinene_hydrate + diphosphate
|
4.2.3.11
sabinene-hydrate synthase
|
–
|
|
|
BRENDA:
BS430213
|
|
|
|
geranyl_diphosphate + H2O <=> cis-sabinene_hydrate + diphosphate
|
4.2.3.11
sabinene-hydrate synthase
|
–
|
|
|
BRENDA:
BS444325
|
|
|
|
geranyl_diphosphate <=> myrcene + (-)-sabinene + linalool + limonene + diphosphate
|
4.2.3.15
myrcene synthase
|
–
|
|
|
BRENDA:
BS379793
|
|
|
|
geranyl_diphosphate <=> alpha-phellandrene + diphosphate
|
4.2.3.20
(R)-limonene synthase
|
–
|
|
|
BRENDA:
BS392054
|
|
|
|
geranyl_diphosphate <=> myrcene + beta-phellandrene + (-)-beta-pinene + alpha-phellandrene + diphosphate
|
4.2.3.52
(4S)-beta-phellandrene synthase (geranyl-diphosphate-cyclizing)
|
–
|
|
|
BRENDA:
BS445495
|
|
|
|
geranyl_diphosphate <=> beta-phellandrene + myrcene + (-)-beta-pinene + diphosphate
|
4.2.3.52
(4S)-beta-phellandrene synthase (geranyl-diphosphate-cyclizing)
|
–
|
|
|
BRENDA:
BS445496
|
|
|
|
geranyl_diphosphate <=> myrcene + (E)-beta-ocimene + (Z)-beta-ocimene + diphosphate
|
4.2.3.23
germacrene-A synthase
|
–
|
|
|
BRENDA:
BS445499
|
|
|
|
geranyl_diphosphate + H2O <=> amorpha-4,11-diene + diphosphate
|
4.2.3.24
amorpha-4,11-diene synthase
|
–
|
|
|
BRENDA:
BS381948
|
|
|
|
geranyl_diphosphate <=> geraniol + linalool + diphosphate
|
4.2.3.43
fusicocca-2,10(14)-diene synthase
|
–
|
|
|
BRENDA:
BS445498
|
|
|
|
2 geranyl_diphosphate <=> (+)-car-3-ene + terpinolene + 2 diphosphate
|
4.2.3.113
terpinolene synthase
|
–
|
|
|
BRENDA:
BS429646
|
|
|
|
2 geranyl_diphosphate <=> (-)-sabinene + terpinolene + 2 diphosphate
|
4.2.3.113
terpinolene synthase
|
–
|
|
|
BRENDA:
BS429647
|
|
|
|
geranyl_diphosphate <=> linalool + (Z)-beta-ocimene + (E)-beta-ocimene + myrcene
|
4.2.3.46
alpha-farnesene synthase
|
–
|
|
|
BRENDA:
BS405240
|
|
|
|
geranyl_diphosphate <=> alpha-terpineol + ocimene + myrcene + linalool
|
4.2.3.24
amorpha-4,11-diene synthase
|
–
|
|
|
BRENDA:
BS406941
|
|
|
|
geranyl_diphosphate <=> tricyclene
|
4.2.3.15
myrcene synthase
|
–
|
|
|
BRENDA:
BS368437
|
|
|
|
geranyl_diphosphate <=> (-)-beta-pinene
|
4.2.3.120
(-)-beta-pinene synthase
|
–
|
|
|
BRENDA:
BS418664
|
|
|
|
geranyl_diphosphate <=> (+)-2-carene
|
4.2.3.15
myrcene synthase
|
–
|
|
|
BRENDA:
BS368436
|
|
|
|
geranyl_diphosphate <=> (+)-limonene
|
4.2.3.15
myrcene synthase
4.2.3.20
(R)-limonene synthase
|
–
–
|
|
|
BRENDA:
BS368434
|
|
|
|
geranyl_diphosphate <=> (E)-beta-ocimene + myrcene
|
4.2.3.46
alpha-farnesene synthase
|
–
|
|
|
BRENDA:
BS405239
|
|
|
|
geranyl_diphosphate <=> (-)-limonene
|
4.2.3.15
myrcene synthase
|
–
|
|
|
BRENDA:
BS368435
|
|
|
|
geranyl_diphosphate <=> (E)-beta-ocimene
|
4.2.3.15
myrcene synthase
|
–
|
|
|
BRENDA:
BS368433
|
|
|
|
ATP + geranyl_diphosphate <=> adenosine_5''-geranyl_triphosphate + diphosphate
|
6.5.1.1
DNA ligase (ATP)
6.5.1.3
RNA ligase (ATP)
|
–
–
|
|
|
BRENDA:
BS411670
|
|
|
|
(2E,6E)-farnesyl_diphosphate + isopentenyl_diphosphate <=> geranyl_diphosphate + diphosphate
|
2.5.1.10
(2E,6E)-farnesyl diphosphate synthase
|
–
|
|
|
BRENDA:
BS355468
|
|
|
|
dimethylallyl_diphosphate + isopentenyl_diphosphate <=> (2E,6E)-farnesyl_diphosphate + geranyl_diphosphate
|
2.5.1.20
rubber cis-polyprenylcistransferase
|
–
|
|
|
BRENDA:
BS355474
|
|
|
|
geranyl_diphosphate + ADP <=> diphosphate + N6-geranyl-ADP
|
2.5.1.27
adenylate dimethylallyltransferase
|
–
|
|
|
BRENDA:
BS388751
|
|
|
|
ATP + geranyl_phosphate <=> ADP + geranyl_diphosphate
|
2.7.4.26
isopentenyl phosphate kinase
|
–
|
|
|
BRENDA:
BS418473
|
|
|
|
geranyl_diphosphate <=> (S)-beta-bisabolene + (S)-beta-macrocarpene
|
5.5.1.17
(S)-beta-macrocarpene synthase
|
–
|
|
|
BRENDA:
BS426433
|
|
|
|
2 dimethylallyl_diphosphate + isopentenyl_diphosphate <=> geranyl_diphosphate + chrysanthemyl_diphosphate + lavandulyl_diphosphate
|
not assigned
|
–
|
|
|
SABIO-RK:
7101
|
|
|
|
n isopentenyl_diphosphate + geranyl_diphosphate <=> Polyprenyl_diphosphate + n diphosphate
|
2.5.1.31
ditrans,polycis-undecaprenyl-diphosphate synthase [(2E,6E)-farnesyl-diphosphate specific]
|
–
|
|
|
SABIO-RK:
12134
|
|